In Pidgin, I can't edit XMPP account details after saving them

Why?

Try disabling this account before editing.

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Correct, if the account is online or enabled and offline, you can’t change the settings.

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Protocol, Username, Domain, and Resource are now no longer grayed out and can be modified.

Is that a question, or are you summarising?

I was adding additional context as it wasn’t clear from the screen shots alone what you were trying to portray.

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